Interactions of Eu3+ and Am3+ with humic acid extracted from soil of Yongkwang in the Okchon Basin of the Korean Peninsula

Summary The stability constants of Eu³⁺ and Am³⁺ with the site specific humic acid (YKHA) have been determined. The humic acid has been extracted from the soil of Yongkwang area belonging geologically to the Okchon Basin of the Korean Peninsula, where the nuclear power plant is located. The total carboxylate capacity, the acidity constant (pKa), and the binding constants with Eu³⁺ and Am³⁺ have been determined for humic acid.     

A Mossbauer study of the magnetic coupling in iron phosphorous trisulfides

The polycrystalline sample of layered compound FePS_3 has been investigated by using M?ssbauer spectroscopy (12K to 300K), magnetic susceptibility measurements, x-ray diffraction and FTIR spectroscopy. The antiferromagnetic order exists below T_N=120.5±1K. The M?ssbauer spectra below T_N indicate that the magnetization axis is perpendicular to the layer of FePS_3, and the divalent iron cations are in their high spin configurations. By fitting the hyperfine field parameters near the Néel temperature, we obtain information on the nature of magnetic interactions in the material. The results show that the magnetic coupling can be treated by the two-dimensional Ising model, and it can be interpreted on the basis of a crystal-field effect.     

Whole-field determination of isoclinic parameter by five-step color phase shifting and its error analysis

Combining color imaging with phase shifting, a technique named five-step color phase shifting is presented to determine the whole-field isoclinic parameter. Relevant theory is derived and explicit conditions for directly determining the isoclinic parameter in the range of [0,π/2] are given. The unloaded light intensity of the model is systematically studied. A color camera recorded five isoclinic images coupled with isochromatics from a plane polariscope with five different settings, respectively. Experiments have been carried out with a circular disk under diametral compression and errors have been analyzed and estimated. This technique utilizes white light, which avoids undefined isoclinics near the locations where the isochromatics exist and will have active effect on experimental stress analysis and structural strength design.     

用Talbot效应及云纹干涉法测试镜面反射体曲率和斜率的灵敏度分析

对用Talbot效应及云纹干涉法测试镜面反射体曲率和斜率的灵敏度进行了分析,同时给出了由于光栅稀密对测试的影响和相应的解释。这对从事这项工作或工程上利用此技术测试物体曲率和斜率提供了一个可行的方案。     

Frame Wavelets with Compact Supports for L^2（R^n）

The construction of frame wavelets with compact supports is a meaningful problem in wavelet analysis. In particular, it is a hard work to construct the frame wavelets with explicit analytic forms. For a given n × n real expansive matrix A, the frame-sets with respect to A are a family of sets in R^n. Based on the frame-sets, a class of high-dimensional frame wavelets with analytic forms are constructed, which can be non-bandlimited, or even compactly supported. As an application, the construction is illustrated by several examples, in which some new frame wavelets with compact supports are constructed. Moreover, since the main result of this paper is about general dilation matrices, in the examples we present a family of frame wavelets associated with some non-integer dilation matrices that is meaningful in computational geometry.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007     

一种新型有机电致微腔结构的双模发射

采用结构Glass／DBR／ITO／NPB／NPB：Alq／Alq／Al制作了有机微腔电致发光器件。将空穴传输材料与发光材料以一定比例混合作为发光层，为了便于对比，在不改变有机层的膜厚的情况下同时制作了传统的异质结微腔器件，发现两种器件的发光光谱有很大不同，器件的复合效率与传统的异质结器件相比也得到了很大提高，这是因为将两种有机材料混合能消除界面势垒，提高器件的复合效率，从而提高了器件的发光性能，实现了微腔双模发射，且两个模式的半峰全宽分别为8nm和12nm。通过进一步优化器件结构可以实现微腔白光发射。     

微加工薄膜变形镜特性分析

 借助测量微加工薄膜变形镜驱动器的面形影响函数，分析了驱动器的电压-位移函数和驱动器之间的线性叠加性;通过对连续面形变形镜拟合像差的理论分析和实验研究，建立了微加工薄膜变形镜电压解耦模型。分析了对前36阶Zernike模式的拟合残差和拟合能力，指出微加工薄膜变形镜仅可用来拟合低级像差并且有较大的拟合能力和较小的拟合残差，而不能拟合高级像差。     

卡尔曼滤波紫外光度法同时测定酱油、食醋中的山梨酸和苯甲酸

在酸性条件下，采用乙酸乙酯萃取、Na2HPO4溶液反萃取分离酱汪、食醋中的山梨酸、苯甲酸，卡尔曼滤波法计算结果，并与比值导数波谱法进行比较。结果表明，卡尔曼滤波法较地数波谱法有较高准确度和精密度，并能监测干扰物质存在与否。用于实际样品分析有更高的可靠性。     

旋涡运动的稳定性与角动量守恒

本文利用角动量作为Liapunov函数建立二维的圆形涡块及涡环在有限或无限区域上的(Liapunov)非线性稳定性.